Antimony trisulfide (Sb2S3) is a chalcogenide material that exhibits large refractive index changes of ~1 between crystalline and amorphous states. Molecular Formula: H 2 Sb: Synonyms: Antimony(III) Molecular Weight: 123.78 g/mol. 6 Chemical Vendors. Sb(III) is particularly appealing for its oxidative stability (compared to Ge2+ and Sn2+) and low toxicity (compared to Pb2+). Solutions of antimony(III) chloride in \(\ce{HCl}\) react when added to excess water to form the basic, white, insoluble salt \(\ce{SbOCl}\). Sigma-Aldrich. CopyCopied, CSID:94667, http://www.chemspider.com/Chemical-Structure.94667.html (accessed 13:28, Jan 6, 2021) Diese lassen sich anschließend vom überschüssigen Antimon(III)-fluorid abdestillieren. ). Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries Abstract Antimony holds a high‐specific capacity as a promising anode material for Na‐ion batteries (SIBs) and much research is focused on solving the poor cycling stability issue associated with its large volume expansion during alloying/dealloying processes. Synonym: Antimony trichloride. IUPAC Name: antimony(3+) CAS Number: 23713-48-6 . For more information contact us at info@libretexts.org or check out our status page at https://status.libretexts.org. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries. Antimony(III) Cite. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries. Linear Formula: SbCl3. IUPAC-Gruppe oder Stickstoffgruppe. Missed the LibreFest? State Key Laboratory of Powder Metallurgy, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083 China. Safety. The sulphuric acid reaction produces SO 2. A STUDY OF THE ION EXCHANGE REMOVAL OF ANTIMONY(III) AND ANTIMONY(V) FROM COPPER ELECTROLYTES. Dates: Modify . Antimony (V) ion - chemical information, properties, structures, articles, patents and more chemical data. and are physiologically tolerated more than trivalent antimony (antimony(III)) compounds (Winship, 1987). 1380 o. Density 6.69 g/cm 3. The types of ionic mobility in these compounds were identified at 150–470 K. Ganz siche… 5 Related Records Expand this section. Antimony(III) oxide is a useful catalyst in the production of polyethylene terephthalate (PET plastic) and the vulcanization of rubber. pricing. In der stabilen Modifikation ist es ein silberglänzendes und sprödes Halbmetall. Contents. Es gehört zur Stoffklasse der Oxide. The electron configuration for antimony is 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 2 4d 10 5p 3. InChI=1S/Sb/q+3 Contents. ANTIMONY CATION (3+) More... +)) Validated by Experts, Validated by Users, Non-Validated, Removed by Users. CopyCopied, FAWGZAFXDJGWBB-UHFFFAOYSA-N The LibreTexts libraries are Powered by MindTouch® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. It is manufactured for use in safety matches, military ammunition, explosives and fireworks. Characteristic Reactions of Antimony Ions (Sb³⁺) Last updated; Save as PDF Page ID 97261; Contributed by James P. Birk; Professor Emeritus (Chemistry) at Arizona State University; Chloride Ion: Aqueous Ammonia: Sodium Hydroxide; Hydrogen Sulfide; Water; Reducing Agents; No Reaction; Most common oxidation states: +3, +5; M.P. Choose from 21 different sets of term:sb = antimony (iii) ion flashcards on Quizlet. Halides of ns2 metal ions have recently regained broad research interest as bright narrowband and broadband emitters. Tianjing Wu. Structural Diversity in Cesium Bismuth Halide Nanocrystals. The known anti- mony(III) based ion exchangers are antimony(llI) arsenate, antimony(III) molybdate", antimony(llI) selenite and antimony(III) tungstate", But a hetero- polyacid ion exchanger based on annmonytlll) has not yet been reported. School of Mineral Processing and Bio‐engineering, … ID of ANTIMONY Cations by Precipitation Reactions : RELEASE DATE: 16 JULY 1997 : LAST UPDATE: 31-July-98 : VERSION HISTORY: 1.0, 1.1, 1.2 ( Context updates) V2.0 ( Text and formatting update - Sep-2009) INTRODUCTION: This is an account on how to detect Antimony ions in solution by simple precipitation reactions. CHEBI:30302 [DBID] UNII:069647RPT5 [DBID] UNII-069647RPT5 [DBID] Predicted - ACD/Labs; Predicted - EPISuite; Predicted - ChemAxon; Predicted data is generated using the ACD/Labs … Antimony(III) sulfate. ANTIMONY IN DRINKING-WATER 2 1.5 Environmental fate The emission of antimony into the human environment … The noble gas electron configuration is: The... See full answer below. Share. Antimony, Sb 3+ Most common oxidation states: +3, +5 M.P. 630 o. B.P. Chenyang Zhang. This article is cited by 83 publications. More... Antimony (3+) is a monoatomic trication and an elemental antimony. 1 Structures Expand this section. Sicherheitshinweise. Characteristics: Brittle, silvery. Im Periodensystem steht es in der 5. Some specialty pigments contain antimony. PubChem CID: 102060556: Structure: Find Similar Structures. 2 Names and Identifiers Expand this … Materials that exhibit large and rapid switching of their optical properties in the visible spectrum hold the key to color-changing devices. More by Yadan Zhou, Wei Feng* Wei Feng . 47, No. Among several industrial applications of antimony compounds, antimony trioxide is largely employed in the production of glassware and ceramics. 19F and 1Н NMR methods were used to study ion mobility in M6Sb4(SO4)3F12 (M = Rb, Cs, NH4) and (NH4)2Sb(SO4)F3 complex antimony(III) sulfate fluorides with alkali cations and ammonium. 337374. Search for more papers by this author . Außerdem dient es als Beizmittel zum Färben und wird bei der Herstellung von Keramik verwendet. Die koptische Bezeichnung für das Schminkpuder Antimonsulfid ging über das Griechische in das Lateinische stibium über. Molecular Weight: 531.71. The toxicity of antimony(III) ion is 10 times higher than that of antimony(V) ion, and antimony(III) has been shown to cause lung cancer (Garbooe et al., 1997). 2005-03-27. Construction of 2D Antimony(III) Selenide Nanosheets for Highly Efficient Photonic Cancer Theranostics. However, antimony purification from liquid system is yet poorly documented. Chenyang Zhang. Antimony trisulfide (Sb 2 S 3) is found in nature as the crystalline mineral stibnite and the amorphous red mineral metastibnite. Sidney E. Creutz, Hongbin Liu, Mitchell E. Kaiser, Xiaosong Li, Daniel R. Gamelin. 2 Names and Identifiers Expand this section. \[\ce{Sb2S3(s) + 3S2^{-}­(aq) <=> 2SbS33­(aq)}\], \[\ce{Sb2S3(s) + 6H^{+}(aq) + 8Cl­^{-}(aq) <=> 2SbCl4^{2-}­(aq) + 3H2S(aq)}\]. Not very active, but reacts with oxygen, sulfur and chlorine at high temperatures. This sulfide is soluble in solutions of hot \(\ce{NaOH}\) which contain excess sulfide ion and in hot, concentrated (12 M) \(\ce{HCl}\). Department of Ultrasound, Sir Run Run Shaw Hospital, Zhejiang University School of Medicine, Hangzhou 310016, P. R. China. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. Antimon(III)-oxid (auch Antimontrioxid genannt) ist eine Antimonverbindung mit der Summenformel Sb2O3. Antimony Trioxide Nanopowder. Watch the recordings here on Youtube! Learn term:sb 3 = antimony (iii) ion with free interactive flashcards. Unless otherwise noted, LibreTexts content is licensed by CC BY-NC-SA 3.0. Have questions or comments? CAS Number: 10025-91-9. ≥99.95% trace metals basis. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite™, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite™, Compounds with the same molecular formula, Search Google for structures with same skeleton. School of Mineral Processing and Bio‐engineering, … Jahrhundert ging der Name Antimon als Bezeichnung auf das Metall über. 2015-12-24. Periode und der 5. (2008). Stibnit)) ist ein chemisches Element mit dem Elementsymbol Sb (von lateinisch Stibium (Grau-)Spießglanz) und der Ordnungszahl 51. Create . 2020-11-29. Hauptgruppe, bzw. Molecular Weight: 228.12. Component Compounds: CID 5354495 (Antimony) CID 783 (Hydrogen) Dates: Modify . Resources Search for: ANTIMONY (III) ION . Antimony has been extensively used in lead alloys, battery grids, bearing metal, cable sheathing, plumber’s solder, pewter, ammunition, sheet, and pipe. Antimony(III) Sulfide Thin Films as a Photoanode Material in Photocatalytic Water Splitting | ACS Applied Materials & Interfaces For the first time, we present exploratory investigations on the performance of thermally evaporated Sb2S3 thin film photoanodes for solar-assisted water-splitting applications. 3, pp. APT (tartar emetic) has been used to induce vomiting in poisoning cases, and antimony compounds such as piperazine antimony tartrate were used as drugs against bilharzia. It also is used in the production of ruby-colored glass and in plastics as a flame retardant. antimony(iii) 23713-48-6 [RN] Antimony [Wiki] ANTIMONY (III) ION. Antimony is dissolved in hot concentrated sulphuric acid, H 2 SO 4, or nitric acid, HNO 3, forming Sb(III) solutions. Learn term:sb = antimony (iii) ion with free interactive flashcards. 2020-12-26. Email. Antimon(III)-fluorid wird als mäßig aktives Fluorierungsmittel, bevorzugt für niedrig schmelzende Fluoride, verwendet. A study of the ion exchange removal of antimony(III) and antimony(V) from copper electrolytes. WEB … Recently, luminescent antimony (III) and bismuth (III) hybrid halide compounds have aroused great research interest. Characteristic reactions of Sb 3+: (Sb(III) is the more stable oxidation state.) Antimon wurde in Form seiner Verbindungen schon in der Bronzezeit als Zuschlag zu Kupfer verwendet, um Bronze herzustellen (Funde von Velem-St. Vid in Ungarn) und auch im Altertum genutzt. SDS; Antimony(III) sulfide. 4 Spectral Information Expand this section. Legal. Create . Choose from 97 different sets of term:sb 3 = antimony (iii) ion flashcards on Quizlet. Search for more papers by this author. 1 Product Result | Match Criteria: Product Name, Property, Description Linear Formula: Sb 2 (SO 4) 3. Antimony(III) oxide, CP. Antimon [antiˈmoːn] (von lateinisch Antimonium, vermutlich von arabisch al-ithmîd(un) (ithmid / إثمد / iṯmid, Antimonsulfid bzw. More... Molecular Weight: 291.52 g/mol. In the presence of \(\ce{HCl}\), either aluminum or iron will reduce \(\ce{Sb^{3+}}\) to \(\ce{Sb}\) metal, which will be deposited as black particles. \[\ce{Sb^{3+}(aq) + 3OH^{-}­(aq) <=> Sb(OH)3(s)}\], \[\ce{Sb(OH)3(s) + OH­^{-}­(aq) <=> Sb(OH)4­^{-}­(aq)}\], \[\ce{Sb(OH)3(s) + 3H^{+}(aq) <=> Sb^{3+}(aq) + 3H2O(l) }\]. Antimon(III)-fluorid ist für den Menschen giftig. Characteristic Reactions of Antimony Ions (Sb³⁺), [ "article:topic", "authorname:jbirk", "Antimony", "showtoc:no" ], https://chem.libretexts.org/@app/auth/2/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FBookshelves%2FAnalytical_Chemistry%2FSupplemental_Modules_(Analytical_Chemistry)%2FQualitative_Analysis%2FCharacteristic_Reactions_of_Select_Metal_Ions%2FAntimony%252C_Sb3, Characteristic Reactions of Select Metal Ions, Characteristic Reactions of Aluminum Ions (Al³⁺), information contact us at info@libretexts.org, status page at https://status.libretexts.org, Characteristic reactions of \(\ce{Sb^{3+}}\): (Sb(III) is the more stable oxidation state. Abstract Antimony, a pollutant of priority interest by United States Environment Protection Agency (USEPA) and Europe Union (EU), is detected in soil and water with elevated concentration due to its extensive use in a variety of industries. Sb(III) reacts with aqueous ammonia to precipitate white \(\ce{Sb(OH)3}\). Under moderately acidic conditions, \(\ce{H2S}\) precipitates red \(\ce{Sb2S3}\). Im 17. Antimony Black. 10783 ≥95.0% ; Sigma-Aldrich pricing. Yadan Zhou. Canadian Metallurgical Quarterly: Vol. Chemical Formula: Sb+ 3. click here for details. 1 Structures Expand this section. Yadan Zhou. Tweet. Main group metal ions antimony (III) and bismuth (III) with external electron shell of s 2 configuration belong to the so-called mercury-like ions. CAS Number: 7446-32-4. 15. 3 Chemical and Physical Properties Expand this section. Antimony(III) oxide has suspected carcinogenic potential for humans. Download. Antimony (3+) Please visit the Antimony element page for information specific to the chemical element of the periodic table. Sodium hydroxide also precipitates \(\ce{Sb(OH)3}\), which is amphoteric and dissolves in an excess of hydroxide and in acids. Antimony does not react with hydrochloric acid in the absence of oxygen. Tianjing Wu. 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